Aldehydes and ketones have higher melting and boiling points than hydrocarbons of equivalent molecular weight. This is due to the attraction between molecule due to the polarity of the carbonyl group. This type of attraction is referred to as dipole-dipole forces of attraction. Show IUPAC Rules for Naming Aldehydes IUPAC and Common names of Aldehydes Methanal (formaldehyde) Ethanal (acetaldehyde) Propanal (propionaldehyde)Butanal (butyraldehyde) Pentanal (valeraldehyde) 2-MethylpropanalThe common names of the aldehydes are derived from the same Latin roots as the corresponding carboxylic acids. In the common system of nomenclature, substituted aldehydes are named as derivative of the straight-chain parent compound. Greek letters are used to indicate the position of the substituents. 2-Phenylbutanal = a-phenylbutyraldehyde 3-Methylpentanal = b-methylvaleraldehyde IUPAC Rules for Naming Ketones 2-Pentanone 3-Pentanone Acetophenone Benzophenone Common Aldehydes and Ketones Acetaldehyde (ethanal) is a colorless, flammable liquid, C2H4O, used to manufacture acetic acid, perfumes, and drugs. Also called aldehyde. Acetone (propanone) is a colorless, volatile, extremely flammable liquid ketone, CH3COCH3, widely used as an organic solvent. Benzaldehyde is a normally colorless aromatic oil, C6H5CHO, obtained naturally, as from the bitter almond, or made synthetically and used in perfumes and as a solvent and a flavoring. Reactions of Aldehydes and Ketones 1o alcohol ------> Aldehyde[O] 2o alcohol ------> Ketone[O] 3o alcohol ------> NR[O] Methanol -----> MethanalOxidizing agents, [O], can be KMnO4/OH1- , H2CrO4, or just oxygen from air is some cases. Oxidation Reactions Tollen's Test for Aldehydes Benedict's or Fehling's Test for Aldehydes Reduction Reactions Addition Reactions All molecule of this general type will be classified as acetals. Keto-enol tautomerism Aldol Condensation In this generalized reaction the a-carbon of one aldehyde forms a bond with the carbonyl carbon of the other aldehyde. How many carbons are in an aldehyde?In formaldehyde, the simplest aldehyde, the carbonyl group is bonded to two hydrogen atoms. In all other aldehydes, the carbonyl group is bonded to one hydrogen and one carbon group.
What is the name for 3 carbon atom?4.2 Alkanes. Why do ketones have 3 carbon atoms?Because the carbonyl group in a ketone must be attached to two carbon groups, the simplest ketone has three carbon atoms.
What classification of compound is CH 3 CHO?Acetaldehyde (IUPAC systematic name ethanal) is an organic chemical compound with the formula CH3CHO, sometimes abbreviated by chemists as MeCHO (Me = methyl). It is a colorless liquid or gas, boiling near room temperature.
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